Monthly Archives: October 2023

The synthesis of meta-arylphenol derivatives via acid-promoted rearrangement of cyclohexadienones

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Org. Biomol. Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3OB01363D, Paper
Hongyan Xie, Minxiang Zhang, Xueyu Fang, Zhaohua Yan, Hua Yao
A highly effective strategy for the synthesis of meta-arylphenol derivatives through the selective rearrangement of 4-alkyl-4-aryl-2,5-cyclohexadienones under metal-free conditions was developed, in which acid-promoted [1,2]-migration of the aryl group at...
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Improved synthesis of DA364, a NIR fluorescence RGD probe targeting αvβ3 integrin

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Org. Biomol. Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3OB01206A, Paper
Open Access Open Access
Rachele Maschio, Federica Buonsanti, Federico Crivellin, Fulvio Ferretti, Luciano Lattuada, Federico Maisano, Laura Orio, Lorena Pizzuto, Raphael Campanella, Anthony Clouet, Camilla Cavallotti, Giovanni Battista Giovenzana
Optical imaging (OI) is gaining increasing attention in medicine as a non-invasive diagnostic imaging technology and as a useful tool for image-guided surgery. OI exploits the light emitted in the...
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Expression of concern: A cascade process for directly converting nitriles (RCN) to cyanamides (RNHCN) via SO2F2-activated Tiemann rearrangement

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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB90149A, Expression of Concern
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Guofu Zhang, Yiyong Zhao, Chengrong Ding
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Base-Mediated Carboxylation of C-Nucleophiles with CO2

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Org. Biomol. Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3OB01367G, Review Article
Wenbin Huang, Yanlong Luo
Carbon dioxide (CO2) is an available, abundant, and renewable C1 resource, which could be converted into value-added chemicals. Due to the inherent thermodynamic stability and kinetic inertness, it is difficult...
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Palladium-catalyzed decarboxylative α-allylation of thiazolidinones and azlactones with sulfonamido-substituted acyclic allylic carbonates

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Org. Biomol. Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3OB01404E, Paper
Han-Wen Rao, Tian-Lan Zhao, Long Wang, Hong-Dan Deng, Yan-Ping Zhang, Yong You, Zhen-Hua Wang, Jian-Qiang Zhao, Wei-Cheng Yuan
A palladium-catalyzed decarboxylative α-allylation of thiazolidinones and azlactones with aza-π-allylpalladium zwitterionic intermediates, in situ generated from sulfonamido-substituted allylic carbonates, is successfully developed. This method allows the formation of a series...
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Photothermal therapy for cancer cells using optically tunable Fe2O3@Au hexagonal nanodisks

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J. Mater. Chem. A, 2023, 11,21365-21372
DOI: 10.1039/D3TA00294B, Paper
Lin Li, Fenglian Qi, Jiong Guo, Jing Fan, Wenxiang Zheng, Murtaza Ghulam, Weizhi Wang, Zihui Meng, Lili Qiu
Anisotropic hexagonal Fe2O3@Au nanodisks (Au NDs) are prepared using a space-confined growth method and the size-tunable NDs, which thus realized the directional design of LSPR properties. The AuNDs are employed in photothermal therapy with biological compatibility and high efficacy.
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Emerging high-entropy coordination compounds and their derivatives for energy application

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J. Mater. Chem. A, 2023, 11,20872-20885
DOI: 10.1039/D3TA03500J, Highlight
Josué M. Gonçalves, José G. Ruiz-Montoya
This highlight focuses on the advancements in high-entropy coordination compounds and their derivatives. It explores their synthesis strategies, effectiveness in catalyzing water electrolysis, and electrochemical performance in secondary batteries.
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A unique octadecahedron SrTiO3 perovskite oxide with a nano step-shaped facet structure for enhanced photoredox and hydrogen evolution performance

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J. Mater. Chem. A, 2023, 11,21046-21057
DOI: 10.1039/D3TA03239F, Paper
Chuyu Wang, Yan Li, Xiaojiao Cai, Dongping Duan, Qibo Jia
The crystal facet and vacancy effect of the octadecahedron SrTiO3 with a nano step-shaped facet structure improve the photocatalytic activity. Furthermore, the cocatalysts-loaded SrTiO3 has advantages in the application of overall water-splitting.
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Reinforcement learning-based design of shape-changing metamaterials

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J. Mater. Chem. A, 2023, 11,21036-21045
DOI: 10.1039/D3TA03119E, Paper
Sergi Bernaus Oliva, Felix T. Bölle, A. T. Las, Xiaoxing Xia, Ivano E. Castelli
We have implemented a new reinforcement learning method able to rationally design unique metamaterial structures, which change shape during operational conditions. We have applied this to design nanostructured silicon anodes for Li-ion batteries.
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Diffusion of bulky organic cations in the 3D/2D heterostructures to form interfacial quasi-2D (N2) phase for tin perovskite solar cells

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J. Mater. Chem. A, 2023, 11,21089-21098
DOI: 10.1039/D3TA03539E, Paper
Ashank Seetharaman, Sudhakar Narra, Parameswaran Rajamanickam, Raghunath Putikam, Ming-Chang Lin, Eric Wei-Guang Diau
A simple forceps-assisted pressing of two thin films with E1 (3D) and N1 (2D) phases to build multilayered perovskite heterostructures for lead-free perovskite solar cell application.
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