Both layered trihydroxide hollow cubes and bismuth oxide derived from MOF templates for high-performance alkaline batteries

Inorg. Chem. Front., 2023, 10,5969-5978
DOI: 10.1039/D3QI00962A, Research Article
Jianwei Wang, Wenhui Wang, Huan Wang, Wenlin Zhang, Yanzhong Zhen, Feng Fu, Bin Xu
A full battery was assembled with the CoNiMn-LDH cathode and the Bi2O3 anode derived from MOF templates, and achieved significant long-term cycling stability.
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Au/UiO-66-Zr nanohybrids: boosting the yield rates of electrochemical ammonia synthesis with the sacrificial effects of faradaic efficiencies

Inorg. Chem. Front., 2023, 10,6086-6104
DOI: 10.1039/D3QI01021J, Research Article
Xiaoyu Qian, Lu Ding, Yanling Zhao, Zhichun Li, Yuanxiu Liao, Jiabin Tan, Xiaobo He
NH3 yield rates are boosted with the sacrificial of a few faradaic efficiencies (FEs). The even & dense loading of small Au nanoparticles on UiO-66-Zr due to NaBH4 bring the optimal yield rate but a moderate FE due to the sacrificial effects of FEs.
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Electron-rich biochar enhanced Z-scheme heterojunctioned bismuth tungstate/bismuth oxyiodide removing tetracycline

Inorg. Chem. Front., 2023, 10,6045-6057
DOI: 10.1039/D3QI01283B, Research Article
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Fuyan Kang, Xiaona Jiang, Yao Wang, Juanna Ren, Ben Bin Xu, Guoyang Gao, Zhanhua Huang, Zhanhu Guo
In the synthesized BC/BWI catalyst, the introduction of biochar and construction of Z-type heterojunctions accelerated the photogenerated carrier separation to reach an efficient removal of tetracycline.
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Ligand substitution reactions afford oxaliplatin-based platinum(IV) complexes bearing axial alkoxido ligands

Inorg. Chem. Front., 2023, 10,6058-6066
DOI: 10.1039/D3QI01562A, Research Article
Zoufeng Xu, Long Lin, Binbin Fu, Fu-Ping Huang, Qiyuan Zhou, Guangyu Zhu, Zhigang Wang
Oxaliplatin-based platinum(IV) complexes bearing axial alkoxido ligands were obtained by substituting the trifluoroacetato ligand. These complexes exhibit enhanced stability and reduced cytotoxicity compared to their carboxylated platinum(IV) analogues.
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Low-coordination single Ni atoms on graphitic C3N4 for nitrite electroreduction to ammonia

Inorg. Chem. Front., 2023, 10,5950-5957
DOI: 10.1039/D3QI01425H, Research Article
Hongyan Zhao, Jiaqi Xiang, Guike Zhang, Kai Chen, Ke Chu
Single Ni atoms on g-C3N4 are verified as an efficient catalyst for electrocatalytic converting NO2 to NH3, which is attributed to the critical role of low-coordination Ni1–N2 moieties in activating and hydrogenating NO2 and retarding the HER.
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Dry approach production of a garnet solid electrolyte membrane for lithium batteries

Inorg. Chem. Front., 2023, 10,6023-6031
DOI: 10.1039/D3QI01319G, Research Article
Qiulin Li, Yiqiu Li, Hao Chen, Hui Liu, Lianjie Li, Jie Song, Maowen Xu, Shu-Juan Bao
Ultrathin garnet solid electrolyte membranes were successfully prepared by dry electrode technology, in addition to investigating the mechanism of membrane formation and electrochemical properties.
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Group 14 metallole dianions as η5-coordinating ligands

Inorg. Chem. Front., 2023, 10,5509-5516
DOI: 10.1039/D3QI01342A, Chemistry Frontiers
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiaofei Sun, Peter W. Roesky
The coordination chemistry of group 14 metallole dianions, compared to monoanionic cyclopentadienides, is underexplored. This perspective reviews η5-coordination in group 14 metallole dianions, revealing their potential in organometallic chemistry.
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Synthesis of chiral high-entropy sulfides for non-linear optical applications

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01214J, Research Article
Open Access Open Access
Nethmi W. Hewage, Gayatri Viswanathan, Philip Yox, Kui Wu, Kirill Kovnir, Georgiy Akopov
Non-centrosymmetric semiconductors may exhibit non-linear optical (NLO) properties.
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A 3D lead chloride hybrid exhibits self-trapped emission and exceptional stability

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01350B, Research Article
Mohamed Saber Lassoued, Qian-Cheng Luo, Yan-Zhen Zheng
A new 3D lead chloride hybrid, (H2MPP)2Pb5Cl14, has been isolated. (H2MPP)2Pb5Cl14 exhibits broadband emission with a large Stokes shift and a high color rendering index (CRI), which is mainly attributed to the self-trapped exciton mechanism (STE).
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Investigating the role of oxygen vacancies in metal oxide for enhanced electrochemical reduction of NO3− to NH3: mechanistic insights

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01536J, Review Article
Sadeeq Ullah, Shiyong Wang, Muhammad Sohail Ahmad, Hafiz M. Adeel Sharif, Qingling Liu, Tetsuya Kida, Aamir Shafique, Majeed Ur Rehman, Gang Wang, Jieshan Qiu
Ammonia (NH3) is a crucial chemical commodity used extensively in fertilizer production and as a renewable potential energy carrier.
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