LiVTeO5: a mid-infrared nonlinear optical vanadium tellurate crystal exhibiting enhanced second harmonic generation activities and notable birefringence

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01715J, Research Article
Yuheng She, Jinmiao Jiao, Zheng Wang, Jing Chai, Song Jie, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li
A novel NLO tellurate crystal, LiVTeO5, was extracted via spontaneous crystallization. It features the attractive merits of a strong SHG response, a large band gap, a wide transmittance range, and a notable birefringence.
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Fabrication of ultrathin two-dimensional MOF nanosheets with cage-like cavities showing excellent adsorption for lead(II)

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01619F, Research Article
Hongwei Sun, Ke-Zhong Wang, Meng-Ru Yao, Cai-Xia Yu, Yue-Hai Song, Jing Ding, Yan-Li Zhou, Dong Liu, Lei-Lei Liu
An ultrathin 2D MOF nanosheet with cage-like cavities was constructed, which showed an outstanding Pb2+ uptake capacity of 738.65 mg g−1 as well as ultrahigh selectivity and anti-interference performance.
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Unraveling the effect of carbon morphology evolution in hard carbons on sodium storage performance

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01497E, Research Article
Huilan Sun, Qiaoyan Zhang, Fei Yuan, Di Zhang, Zhaojin Li, Qiujun Wang, Huan Wang, Bo Wang
Na ions can be effectively inserted into carbon layers with suitable spacing and pseudo-graphitic domains play a crucial role in sodium storage. The plateau capacity is positively correlated with the proportion of pseudo-graphitic domains.
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A hydrolytically stable oxo-rhenium(V) antitumor agent for synergistic combination therapy with cisplatin: from synthesis and mechanistic studies to toxicity assessment in zebrafish

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01653F, Research Article
Shreyas P. Vaidya, Manikandan M, Sushanta Chhatar, Saurabh Dey, Chinmoy Patra, Malay Patra
A hydrolytically stable oxo-Re(V) complex presents potent in vitro antitumor activity as a single agent or in combination with cisplatin and negligible toxicity in zebrafish.
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Built-in electric field induced interfacial charge distributions of Ni2P/NiSe2 heterojunction for urea-assisted hydrogen evolution reaction

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01459B, Research Article
Yiqiang Sun, Wenwen Cao, Xuening Ge, Xiaodong Yang, Yong Wang, Yuan Xu, Bo Ouyang, Qi Shen, Cuncheng Li
Herein, a built-in electric field strategy to obtain efficient heterogeneous Ni2P/NiSe2 bifunctional electrocatalysts for both the hydrogen evolution reaction and the urea oxidation reaction is reported.
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Dithiocarbazate–Zn(II) complexes for photodynamic therapy and chemotherapy against lung cancer

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01777J, Research Article
JunGang Deng, YouRu Wu, AiLi Li, WeiPing Pan, LiXia Hou, DaQi Wu, ZhenLei Zhang, Feng Yang, Yi Gou
The Zn(II) complex could efficiently produce ˙O2 to damage lung cancer cells by photodynamic therapy. Simultaneously, the complex can cause cell damage by chemotherapy.
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Current progress in metal–organic frameworks and their derivatives for electrocatalytic water splitting

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01468A, Review Article
Yujung Chen, Peisen Liao, Kehan Jin, Yun Zheng, Huaiyu Shao, Guangqin Li
For electrocatalytic water splitting, MOFs can be optimized through structural modification, plane design and synergetic composite systems, and the annealing process further expands the types of MOF-based electrocatalytic materials.
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Synergetic microstructure engineering by induced ZB/WZ twin boundaries and S vacancies in a Zn0.5Cd0.5S-based S-scheme photocatalyst for highly efficient photocatalytic hydrogen production

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01187A, Research Article
Yuhao Zhang, Dingze Lu, Zhennan Wang, Min Zhou, Kiran Kumar Kondamareddy, Jing Li, Huiqing Fan, Dezhong Cao, Wingkei Ho
Development of structurally unique Zn0.5Cd0.5S (with twin structure and S vacancies) and a Zn0.5Cd0.5S-based metal–organic framework for photocatalytic applications.
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Structural confinement toward suppressing concentration and thermal quenching for improving near-infrared luminescence of Fe3+

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01649H, Research Article
Fangyi Zhao, Yuhe Shao, Zhen Song, Quanlin Liu
To enhance near-infrared luminescence, we introduce Fe3+ and Yb3+ ions to Sr9Ga(PO4)7 and utilize the structural confinement effect to selectively control energy transfer pathways so as to suppress luminescence concentration and thermal quenching.
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Manipulating pre-equilibria in olefin polymerization catalysis: backbone-stiffening converts a living into a highly active salan-type catalyst

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01537H, Research Article
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dmitry V. Uborsky, Mikhail I. Sharikov, Georgy P. Goryunov, Kristina M. Li, Anna Dall'Anese, Cristiano Zuccaccia, Antonio Vittoria, Teresa Iovine, Gianluigi Galasso, Christian Ehm, Alceo Macchioni, Vincenzo Busico, Alexander Z. Voskoboynikov, Roberta Cipullo
Stiffening the catalyst backbone of a slow salan-type catalyst converts it into a highly active indanosalan catalyst, producing highly isotactic PP with an activity rivalling the most productive known salan-catalyst, with much higher MW capability.
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