Site occupation and upconversion process enabled multicolor emission in a Gd3GaO6:Bi3+,Er3+ phosphor for quad-mode anti-counterfeiting

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01525D, Research Article
Zhijun Li, Zeyu Lyu, Pengcheng Luo, Shuai Wei, Chengyu Zhuo, Dashuai Sun, Sida Shen, Hongpeng You
Enabled by the site occupation dependent emission of Bi3+ and the upconversion process dependent emission of Er3+, quad-mode anti-counterfeiting with four distinguishable images is achieved with only the Gd3GaO6:Bi3+,Er3+ phosphor.
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Synthesis, characterization and electrochemical lithium-ion storage properties of sulfonylcalix[4]quinone

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01682J, Research Article
Meng Zhang, Yilin Lin, Weiwei Huang
Sulfonylcalix[4]quinone bearing four sulfonyl-bridged groups was designed and synthesized for the first time and can compensate for the vacancy in preparation and electrochemical applications of thiacalix[n]quinone compounds.
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Reduced-Dimensional Perovskites with Dithioketal-Containing Intercalating Cations for Near-Infrared Light-Emitting Diodes

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01512B, Research Article
Wenxuan Li, Guoying Yao, Yilan Zhang, Lingjiao Zhang, Sujuan Hu, Chuan Liu, Baiquan Liu, Tao Zeng, Zhenyu Yang
Reduced-dimensional (RD) metal halide perovskites (MHPs) have received much attention from scientific researchers for their highly tunable optoelectronic properties and solution processability. To date, the large cation candidates for constructing...
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Lead-Free 3D Hybrid Perovskites based on Aziridinium Cation

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI00872J, Research Article
Olesia I. Kucheriv, Valerii Y. Sirenko, Hanna R. Petrosova, Vadim A. Pavlenko, Sergiu Shova, Il'ya A. Gural'skiy
3D hybrid organic-inorganic halide perovskites attract considerable attention due to their outstanding physical properties and promising applications in photovoltaics and light-emitting diodes. Lead-based hybrid perovskites are the most studied and...
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Soft seed-mediated dimensional control of metal–organic framework nanocrystals through oil-in-water microemulsion

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01567J, Research Article
Jaedeok Lee, Suhyeon Park, Seojeong Woo, Cheongwon Bae, Yuri Jeon, Mingyu Gu, Jeongeon Kim, Yeram Kim, Sang Yong Nam, Jong Hwa Jung, Juyeong Kim
Metal–organic framework (MOF) nanocrystals with high surface area and morphological tunability have shown great potential for a wide range of industrial applications when compared with their bulk counterparts. However, achieving...
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Th@C2(8)-C84 and Th@Cs(15)-C84: impact of actinide metal ions on the electronic structure of actinide endohedral metallofullerenes

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01215H, Research Article
Ning Chen, Yang-Rong Yao, Tiantian Cao, Qingyu Meng, Ze Fu, Yi Shen, Qin Wang, Yingjing Yan, Bing Zhao, Wenxia Wang, Khaoula Merimi, Antonio Rodriguez-Fortea
Two novel thorium-based endohedral metallofullerenes (EMFs), Th@C2(8)-C84 and Th@Cs(15)-C84, have been successfully synthesized and fully characterized by MALDI-TOF mass spectrum, single-crystal X-ray diffraction, UV-vis-NIR spectroscopy, and cyclic voltammetry. The molecular...
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Abiotic Transformations of Nitrogen mediated by Iron Sulfides and related species from Early Earth to Catalyst Design

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01553J, Review Article
C. Felipe Garibello, Daniel S Eldridge, Francois Malherbe, Rosalie K Hocking
Nitrogen fixation and the cycles of nitrogen on Earth are key to life as we know it and are critical to both life and modern agriculture. Despite its importance, there...
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An eco-friendly electrolyte additive for high-power primary aqueous Mg-air batteries

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01223A, Research Article
Bingjie Ma, Wenbin Jiang, Liuzhang Ouyang, Hai-Wen Li
The performance of aqueous Mg-air batteries is predominantly limited by two factors: the high polarization effect caused by the adherence of surface passive film, and the low efficiency resulting from...
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Achieving Broadband Ultraviolet to Mid-Infrared Transparency in Germanate-based Nonlinear Optical Crystals Cs3REGe3O9 (RE = Y, Gd)

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01807E, Research Article
Jinmiao Jiao, Conggang Li, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu
Nonlinear optical (NLO) materials currently attract significant interest and hold paramount importance in the optoelectronic field. Nevertheless, the fabrication of NLO crystals capable of transmitting ultraviolet to mid-infrared wavelengths remains...
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Unlocking the catalytic potential of nickel sulfide for sugar electrolysis: green hydrogen generation from kitchen feedstock

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01686B, Research Article
Supriya A. Patil, Atul C. Khot, Kalyani D. Kadam, Hoa Thi Bui, Hyunsik Im, Nabeen K. Shrestha
The first-ever demonstration of Ni7S6/NF-based electrolyzer with sugar or orange-juice as active electrolyte for an alternative anodic oxidation reaction in water-electrolysis and achieving a higher rate of green-hydrogen at a lower cell voltage.
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