Sheet-Like Silicalite-1 Single Crystals with Embedded Macropores Displaying Superior Catalytic Performance

Posted on 13 October 2023 by Yanfei Zhang

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01712E, Research Article

Yanfei Zhang, Liang Qi, Xiaomin Zhang, Qike Jiang, Peng Lu, Lei Xu, Alexis T. Bell
Unique sheet-like Silicalite-1 single crystals containing intracrystalline macropores (HMS-Silicalite-1) were prepared by urea-assisted, dry-gel synthesis, which uses mesoporous silica spheres (MSS) as both the silica precursor and the macropore template....
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Luminescence Detection of CH2Cl2 via Varying Cu∙∙∙Cu Interaction in a Flexible Porous Coordination Polymer

Posted on 13 October 2023 by Wei-Jie Zhang

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01723K, Research Article

Wei-Jie Zhang, Wan-Tao Chen, Chen-Hui Li, Wen-Zhu Sun, Jia-Wen Ye, Ling Chen, Hai-Ping Wang, Xiao-Ming Chen
Due to the weakness of interaction between chlorohydrocarbon and host framework, the development of reversible and vapochromic coordination polymer (CP)-based luminescence sensors to CH2Cl2 with fast response is still challenging....
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Advances in research on the inhibitory effect of 3D current collector structures for lithium dendrites

Posted on 13 October 2023 by Song-Bai Xiang

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01290E, Review Article

Song-Bai Xiang, Yu Fu, Cheng-Ri Yin, Yue Hou, Hailing Tian, Zhenxing Yin
Lithium is considered the "Holy Grail" of anode materials in lithium metal batteries, due to its extremely low electrochemical potential and high specific capacity. However, during the charging/discharging process, the...
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Supercritical relaxor phase boundary for ultrahigh electrostrictive properties

Posted on 13 October 2023 by Qinghu Guo

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01636F, Research Article

Qinghu Guo, Dong-Xu Li, Zhonghua Yao, Huajun Sun, Hua Hao, Hanxing Liu, Shujun Zhang
Electrostrictive materials have been actively studied for the applications in precision machinery, laser communication, and biological microscopy due to their numerous advantages, including high resolution, negligible hysteresis, low heat dissipation,...
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Triggering synergistic electronic promoting effect through oxygen doping to promote electrochemical nitrogen reduction on metal-free electrocatalyst

Posted on 13 October 2023 by Na Xu

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01673K, Research Article

Na Xu, Qiyang Cheng, Mengfan Wang, Yanzheng He, Haoqing Ji, Federico Rosei
Electrocatalytic nitrogen reduction reaction (NRR) as an alternative approach to the energy-intensive Haber-Bosch process for artificial ammonia synthesis has attracted extensive attention. Previous reports have suggested that metal-free electrocatalyst, such...
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MnBr(CO)5: a commercially available highly active catalyst for olefin hydrosilylation under ambient air and green conditions

Posted on 13 October 2023 by Anthony Vivien

Green Chem., 2023, 25,7721-7728
DOI: 10.1039/D3GC02385K, Paper

Anthony Vivien, Laurent Veyre, Raphaël Mirgalet, Clément Camp, Chloé Thieuleux
Commercially available MnBr(CO)₅ was found to be a remarkable catalyst for olefin hydrosilylation reactions using a wide range of olefins and silanes. This system tolerates unpurified substrates and can be used in green solvents under ambient air.
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Designing an enzyme assembly line for green cascade processes using bio-orthogonal chemistry

Posted on 13 October 2023 by Li Qiao

Green Chem., 2023, 25,7547-7555
DOI: 10.1039/D3GC01898A, Paper

Open Access

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Li Qiao, Zhiyuan Luo, Ru Wang, Xiaolin Pei, Shujiao Wu, Haomin Chen, Tian Xie, Roger A. Sheldon, Anming Wang
Linear orderly combi-crosslinked enzymes (O-CLEs) were designed and constructed for green cascade catalysis using bio-orthogonal chemistry.
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Novel elastic rubbers from CO2-based polycarbonates

Posted on 13 October 2023 by Giulia Chiarioni

Green Chem., 2023, 25,7612-7626
DOI: 10.1039/D3GC02374E, Paper

Open Access

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Giulia Chiarioni, Martin van Duin, Paolo P. Pescarmona
We report the synthesis of novel elastic rubbers based on polycarbonates prepared by the terpolymerisation of CO₂ with a long-alkyl-chain epoxide and an unsaturated epoxide.
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Levoglucosenone to 3D-printed green materials: synthesizing sustainable and tunable monomers for eco-friendly photo-curing

Posted on 13 October 2023 by Amandine L. Flourat

Green Chem., 2023, 25,7571-7581
DOI: 10.1039/D3GC01833D, Paper

Amandine L. Flourat, Lorenzo Pezzana, Sabrina Belgacem, Abdouramane Dosso, Marco Sangermano, Sami Fadlallah, Florent Allais
Novel monomers were prepared through a chemo-enzymatic route from cellulose-based levoglucosenone and polymerized via thiol-ene click-chemistry. The resulting materials proved suitable for 3D-printing, offering well-defined three-dimensional objects.
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Highly efficient biosynthesis of 2,4-dihydroxybutyric acid by a methanol assimilation pathway in engineered Escherichia coli

Posted on 13 October 2023 by Xianjuan Dong

Green Chem., 2023, 25,7662-7672
DOI: 10.1039/D3GC02083E, Paper

Xianjuan Dong, Chao Sun, Jing Guo, Xiangyu Ma, Mo Xian, Rubing Zhang
2,4-Dihydroxybutyric acid production via a methanol assimilation pathway is a green and eco-friendly process without carbon loss.
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