Structural distortion by alkali metal cations modulates the redox and electronic properties of Ce3+ imidophosphorane complexes

Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC04262F, Edge Article
Open Access Open Access
Andrew C. Boggiano, Chad M. Studvick, Alexander Steiner, John Bacsa, Ivan A. Popov, Henry S. La Pierre
Structural distortion of the secondary coordination sphere driven by the incorporation of an alkali metal in Ce3+ imidophosphorane complexes tunes the Ce3+/4+ oxidation potential.
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