Activation of non-polar bonds by an electron-rich gallagermylene

Chem. Commun., 2024, 60,2902-2905
DOI: 10.1039/D3CC06223F, Communication
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Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Anna Bücker, Alexander Gehlhaar, Christoph Wölper, Stephan Schulz
The electron-rich acyclic germylene LGa(μ–Cl)GeArMes (1) activates unpolar bonds as is shown in oxidative addition reactions with H2 and P4, yielding L(Cl)GaGe(H)2ArMes (2) and L(Cl)Ga(P4)GeArMes (3).
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