Phosphite–imidazole catalyzed N-formylation and N-acylation of amines

Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01306E, Paper
Babak Kaboudin, Hesam Esfandiari, Meysam Kakavand, Masoumeh Sohrabi, Elahe Yousefian Amirkhiz, Abdollah Neshat, Teru Kawazoe, Haruhiko Fukaya, Hikaru Yanai
The N-formylation reaction of amines with DMF as a formylating agent was developed. N-Sulfonyl amidines were also obtained in good to excellent yields by the reaction of sulfonamides with DMF under similar conditions.
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