Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02261G, Paper
DOI: 10.1039/D3DT02261G, Paper
Bapan Samanta, Riya Ghosh, Rakesh Mazumdar, Shankhadeep Saha, Sayani Maity, Biplab Mondal
A Co(II) complex, [CoII(L)2(H2O)2](ClO4)2, [L = bis(3,5-dimethylpyrazolyl)methane] in acetonitrile at −40 °C, in presence of H2O2 and NEt3 afforded [CoIII(L)2(O22−)]+, 1a. Addition of NO gas to this resulted in [CoII(L)2(NO3)]ClO4, (2) via a putative Co(II)-peroxynitrite intermediate.
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A Co(II) complex, [CoII(L)2(H2O)2](ClO4)2, [L = bis(3,5-dimethylpyrazolyl)methane] in acetonitrile at −40 °C, in presence of H2O2 and NEt3 afforded [CoIII(L)2(O22−)]+, 1a. Addition of NO gas to this resulted in [CoII(L)2(NO3)]ClO4, (2) via a putative Co(II)-peroxynitrite intermediate.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry