Novel nitrogen-rich lanthanum nitrides induced by the ligand effect under pressure

Dalton Trans., 2023, 52,14142-14150
DOI: 10.1039/D3DT01724A, Paper
Bo Jin, Yuanyuan Liu, Zhen Yao, Shuang Liu, Peng Wang
Unique tri-coordinated atoms with alternate sp2 and sp3 hybridizations are formed in the N18 ring of LaN8. The ligand effect of the introduced La atom on the N10 cage induces the structural evolution from Ī3m-N10 to Imm2-LaN10.
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