NHC-Catalyzed Radical Acylation of Cycloalkyl Silyl Peroxides to Access 1,6-, 1,7-, and 1,8-Diketones

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC04765B, Communication
Chaolei Liu, Jingyi Wang, Xinlong Liu, Jie Feng, Ding Du
An unprecedented N-heterocyclic carbene (NHC)-catalyzed radical acylation of cycloalkyl silyl peroxides was developed using readily available aldehydes as the acylating agents. This protocol provides an exceptionally useful method for the...
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