Cyclometalated C^N diphosphine ruthenium catalysts for Oppenauer-type oxidation/transfer hydrogenation reactions and cytotoxic activity

Catal. Sci. Technol., 2023, 13,5267-5279
DOI: 10.1039/D3CY00676J, Paper
Open Access Open Access
Dario Alessi, Pierfrancesco Del Mestre, Eleonora Aneggi, Maurizio Ballico, Antonio P. Beltrami, Marta Busato, Daniela Cesselli, Alexandra A. Heidecker, Daniele Zuccaccia, Walter Baratta
The neutral ruthenium cyclometalated complexes [Ru(C^N)(η2-OAc)(dppb)] proven to be efficient catalysts in Oppenauer-type oxidation and transfer hydrogenation reactions with TOF up to 14 300 h−1 and show cytotoxic activity against U87 cancer cells.
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