Variation from Closed-Shell to Open Shell Electronic Structures in Oligothiophene Bis(dioxolene) Complexes

Chem. Sci., 2023, Accepted Manuscript
DOI: 10.1039/D3SC02341A, Edge Article
Open Access Open Access
David Shultz, Paul D. Miller, Joshua Mengell, Martin Kirk, Lukasz Wojtas
A series of oligothiophene bis(dioxolene) complexes, SQ-Thn-SQ (SQ = S = ½ TpCum,MeZnII(3-tert-butyl-orthosemiquinonate); TpCum,Me = tris(5-cumenyl-3-methylpyrazolyl)borate anion) have been synthesized, structurally characterized, and studied as a function of the number...
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