Heteroanion induced structural asymmetricity centered on Ru sites switches the rate-determining step of acid water oxidation

Energy Environ. Sci., 2024, 17,1885-1893
DOI: 10.1039/D3EE03396A, Communication
Ding Chen, Hongyu Zhao, Ruohan Yu, Kesong Yu, Jiawei Zhu, Jixiang Jiao, Xueqin Mu, Jun Yu, Jinsong Wu, Shichun Mu
The intervening Se induces the structural asymmetricity of Ru-S6 octahedrons and then regulates the electronic structure of the active Ru site, which possesses excellent acid water oxidation performance as an Ir-free catalyst.
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