Manipulating pre-equilibria in olefin polymerization catalysis: backbone-stiffening converts a living into a highly active salan-type catalyst

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01537H, Research Article
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dmitry V. Uborsky, Mikhail I. Sharikov, Georgy P. Goryunov, Kristina M. Li, Anna Dall'Anese, Cristiano Zuccaccia, Antonio Vittoria, Teresa Iovine, Gianluigi Galasso, Christian Ehm, Alceo Macchioni, Vincenzo Busico, Alexander Z. Voskoboynikov, Roberta Cipullo
Stiffening the catalyst backbone of a slow salan-type catalyst converts it into a highly active indanosalan catalyst, producing highly isotactic PP with an activity rivalling the most productive known salan-catalyst, with much higher MW capability.
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