A co-crystal of heterobicyclic isomers as a product of the cyclocondensation reaction of 3,4-diaminofurazan with diethyl-2-oxosuccinate

CrystEngComm, 2023, 25,5413-5419
DOI: 10.1039/D3CE00769C, Paper
Galina V. Romanenko, Sergey V. Fokin, Svyatoslav E. Tolstikov, Gleb A. Letyagin, Victor I. Ovcharenko, Kirill V. Strizhenko, Aleksei B. Sheremetev
Using SC XRD, it was proved that the cyclocondensation of 3,4-diaminofurazan with diethyl-2-oxosuccinate gives two products, being structural isomers – derivatives of furazano[3,4-b]pyrazin-6-one (2) and furazano[3,4-b][1,4]diazepin-7-one (6).
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