Alscholarines A and B, two rearranged monoterpene indole alkaloids from Alstonia scholaris

Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01424J, Paper
Guanqun Zhan, Fuxin Zhang, Kailing Yang, Tao Yang, Ruixi Zhou, Wenwen Chen, Jingwei Zhang, Xinxin Zhang, Zengjun Guo
Alscholarines A–B, featuring an imidazole ring fused with a 6/5/6/6 tetracyclic skeleton and an unusual 7-oxa-1-azabicyclo[3.2.1]octane moiety with a 6/5/6/6/5 ring system, respectively, were isolated from Alstonia scholaris.
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