Tailoring the d-band center of porous CoS2 nanospheres via low-electronegative Fe for weakened OH* adsorption and boosted oxygen evolution

Inorg. Chem. Front., 2023, 10,5668-5677
DOI: 10.1039/D3QI00902E, Research Article
Heyuan Chen, Wei Wu, Suhao Chen, Zichen Wang, Runzhe Chen, Niancai Cheng
The doping of low-electronegative Fe changes the charge distribution of Co sites as well as downshifts the d-band center of Co sites to reduce the binding barrier between Co sites and *OH.
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