Chemoselective C(sp)–H borylation of terminal alkynes catalyzed by a bis(N-heterocyclicsilylene) manganese complex

Inorg. Chem. Front., 2023, 10,6067-6076
DOI: 10.1039/D3QI01033C, Research Article
Himani Ahuja, Harleen Kaur, Rebeca Arevalo
The manganese(II) complex [Mn(SiNSi)Cl2] (SiNSi = 2,6-[EtNSi(NtBu)2CPh]2C5H3N) is an efficient catalyst for the chemoselective C(sp)–H borylation of terminal alkynes.
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