Divergent 1,2-Carboallylation of Terminal Alkynes Enabled by Metallaphotoredox Catalysis with Switchable Triplet Energy Transfer

Chem. Sci., 2023, Accepted Manuscript
DOI: 10.1039/D3SC04645A, Edge Article
Open Access Open Access
Jian Qin, Zhuzhu Zhang, Yi Lu, Shengqing Zhu, Lingling Chu
We report a metallaphotoredox strategy for stereodivergent three-component carboallylation of terminal alkynes with allylic carbonates and alkyl trifluoroborates. This redox-neutral dual catalytic protocol utilizes commercially available organic photocatalyst 4CzIPN and...
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