Room temperature stable E,Z-diphosphenes: their isomerization, coordination, and cycloaddition chemistry

Chem. Sci., 2023, 14,10944-10952
DOI: 10.1039/D3SC04506D, Edge Article
Open Access Open Access
Jieli Lin, Shihua Liu, Jie Zhang, Hansjörg Grützmacher, Cheng-Yong Su, Zhongshu Li
N-Heterocyclic vinyl substituted diphosphenes 2b in both E- and Z-isomers have been isolated and crystallographically characterized. They exhibit reversible photo- and thermally stimulated EZ isomerization mimicking their carbon analogue.
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