Mechanism and origins of cobalt-catalyzed ligand-controlled regiodivergent C–H functionalization of aldehydes with enynes

Dalton Trans., 2023, 52,13946-13954
DOI: 10.1039/D3DT02570E, Paper
Jing-Wen Zhang, Xiao-Jun Liu, Jian Zhang, Jian-Biao Liu
Mechanistic studies reveal that σ-bond metathesis is more challenging and its feasibility is highly dependent on the ligand bite angle.
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