Pd(II)-catalyzed hydroarylations/hydroalkenylations of terminal alkynes: regioselective synthesis of allylic, homoallylic, and 1,3-diene systems

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC00049H, Communication
Jivan Shinde, Sundaram Suresh, Veerababurao Kavala, Ching-Fa Yao
A Pd-catalyzed regioselective hydroarylation/hydroalkenylation of terminal alkynes containing a heteroatom has been developed via carbopalladation for the synthesis of allylic ethers, amines, homoallylic alcohols and 1,3-dienes.
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