A selenium-based “alkahest”: reactive dissolutions of metals and metal compounds with n-alkylammonium polyselenide solutions

Inorg. Chem. Front., 2023, 10,6032-6044
DOI: 10.1039/D3QI01632C, Research Article
Jonathan W. Turnley, Swapnil D. Deshmukh, Victoria M. Boulos, Robert Spilker, Christian J. Breckner, Kevin Ng, Judy Kuan-Yu Liu, Jeffrey T. Miller, Hilkka I. Kenttämaa, Rakesh Agrawal
Solutions containing n-alkylammonium polyselenides constitute a new reactive solvent system. This reactive dissolution chemistry is broadly generalizable and can enable solution processed synthesis of a wide range of metal chalcogenide semiconductors, both as thin films and nanoparticles.
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