ANbO3 (A = Na, K) and (A′ = Ca, Sr) composite oxides for oxidative coupling of methane and oxidative dehydrogenation of ethane: perovskite vs. layered perovskite

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY01055D, Paper
Junwei Xu, Xusheng Zhong, Rumeng Ouyang, Xiuzhong Fang, Xianglan Xu, Xiang Wang
For OCM, the reactivity of regular perovskite is better than layered perovskite due to its high-temperature crystal phase. For ODHE, the C2H4 selectivity of layered perovskite is better than regular perovskite due to its weaker Nb–O bond strength.
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