Author Archives: Kai Li

Temperature induced single-crystal to single-crystal transformation of uranium azide complexes

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Chem. Commun., 2024, 60,2966-2969
DOI: 10.1039/D4CC00546E, Communication
Open Access Open Access
Kai Li, Thayalan Rajeshkumar, Yue Zhao, Tianwei Wang, Laurent Maron, Congqing Zhu
A temperature-induced single-crystal to single-crystal transformation was observed in monoanionic N–P ligand-supported uranium azide complexes.
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Synthesis and reactivity of a uranium(IV) complex supported by a monoanionic nitrogen–phosphorus ligand

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Inorg. Chem. Front., 2023, 10,5622-5633
DOI: 10.1039/D3QI01447A, Research Article
Kai Li, Jialu He, Yue Zhao, Congqing Zhu
A monoanionic N–P ligand L3 with a pendant dimethylamino group was designed. Species with multiple U–C bonds—a rare example of a metallafluorene containing an actinide element—and clusters with multiple U–M bonds were isolated.
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