Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC03222A, Edge Article
DOI: 10.1039/D3SC03222A, Edge Article
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Karan Goyal, Garrett A. Kukier, Xiangyang Chen, Aneta Turlik, K. N. Houk, Richmond Sarpong
A transformation of spiro[4.4]nonatrienes to aryl-substituted, enantioenriched annulated fulvenes is reported. DFT calculations and empirical results support a novel mechanism of reaction involving a 1,5-vinyl shift from a vinyl–palladium species.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
A transformation of spiro[4.4]nonatrienes to aryl-substituted, enantioenriched annulated fulvenes is reported. DFT calculations and empirical results support a novel mechanism of reaction involving a 1,5-vinyl shift from a vinyl–palladium species.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry