Nitrene transfer from a sterically confined copper nitrenoid dipyrrin complex

Chem. Sci., 2023, 14,10847-10860
DOI: 10.1039/D3SC03641C, Edge Article
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kurtis M. Carsch, Sasha C. North, Ida M. DiMucci, Andrei Iliescu, Petra Vojáčková, Thomas Khazanov, Shao-Liang Zheng, Thomas R. Cundari, Kyle M. Lancaster, Theodore A. Betley
A dipyrrin-supported copper complex mediates C–H bond amination and aziridination of exogenous substrates using electron-deficient arylazides, proceeding through copper-nitrene adducts.
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