Crystal structure, phase width, and physical properties of the barium tetrel selenides Ba6Si2−xGexSe12 (x = 0, 0.5, 1, and 1.5) with ultralow thermal conductivity

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02516K, Paper
Luke T. Menezes, Abdeljalil Assoud, Holger Kleinke
The crystal structures and physical properties of the compounds Ba6Si2−xGexSe12 (x = 0, 0.5, 1, and 1.5) were determined by Rietveld refinements. Synchrotron radiation was used to study the Si/Ge disorder and the disordered Se22− pairs.
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