Tuning catalytic activity with steric and electron-withdrawing effects of a porphyrin substituent

Catal. Sci. Technol., 2023, 13,5280-5289
DOI: 10.1039/D3CY00758H, Paper
Lulu Jiang, Yosuke Imanaka, Hiroshi Fujii
The reactivity, spectroscopic, and kinetic studies of the catalytic reactions showed that the catalytic activity is determined by the balance of the rates of the formation, reaction, and decomposition reactions of the reactive intermediate.
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