New insights into controlling radical migration pathways in heme enzymes gained from the study of a dye-decolorising peroxidase

Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC04453J, Edge Article
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marina Lučić, Michael T. Wilson, Jacob Pullin, Michael A. Hough, Dimitri A. Svistunenko, Jonathan A. R. Worrall
We show that radical migration in a heme peroxidase can be controlled and directed to a rationally designed site through simply removing an oxygen atom form the protein structure.
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