Borane catalyzed transesterification of tert-butyl esters using α-aryl α-diazoesters

Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01548C, Communication
Maying Yan, Lei Xiao, Jiangkun Xiong, Lvnan Jin, Douglas W. Stephan, Jing Guo
B(C6F5)3 catalyzed transesterification of unsaturated tert-butyl esters with α-aryl α-diazo esters occurs in good yields (up to 99%) under mild reaction conditions, leaving the CC bonds intact.
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