Unusual cleavage of phosphaalkynes triple bond in the coordination sphere of transition metals

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT02472E, Communication
Mehdi Moussa, Eva-Maria Rummel, Maria Eckhardt, Christoph Riesinger, Manfred Scheer
The reaction of RC≡P (R = Me, tBu, iPr) with Co2(CO)8 and Fe2(CO)9 under mild conditions led to unpredictable fragmentations of the C-P triple bond and subsequent formation of clusters...
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