Role of cavities created by azobenzene-modified UiO-66 in bulky ionic liquid for high photoresponsive CO2 uptake behavior

J. Mater. Chem. A, 2023, 11,21058-21065
DOI: 10.1039/D3TA04786E, Paper
Meng-Meng Li, Manish Kumar Dinker, Yang Liu, Mingrui Zuo, Lifeng Ding, Xiao-Qin Liu, Lin-Bing Sun
Cavities (intrinsic/extrinsic) are created in porous liquid by ionic liquid surrounding MOF with pendant azo-group which bends under UV-light and dissipates the extrinsic cavities. Thus, a large change in CO2 uptake is achieved under UV/Vis light.
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