Guest exchange in a biomimetic ZnII cavity-complex: kinetic control by a catalytic water, through pore selection, 2nd sphere assistance, and induced-fit processes

Inorg. Chem. Front., 2023, 10,5772-5781
DOI: 10.1039/D3QI01271A, Research Article
Open Access Open Access
N. Nyssen, N. Giraud, J. Wouters, I. Jabin, L. Leherte, O. Reinaud
The kinetics of ligand exchange at a ZnII center confined in a biomimetic environment is studied.
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