Dalton Trans., 2023, 52,13858-13863
DOI: 10.1039/D3DT02366D, Communication
DOI: 10.1039/D3DT02366D, Communication
Nisha K. Agrawal, S. Gayathridevi, Soumya R. Dash, Kumar Vanka, Balaji R. Jagirdar
Treatment of trans-[Ir(H)(N)2(iPr)4(POCOP)(DMAP)][BAr4f] (2) with H2 (1 bar) under ambient conditions (298 K) results in the formation of a trans-[Ir(H)(η2-H2)(iPr)4(POCOP)(DMAP)][BAr4f] (3) complex. H-atom site exchange between the H2 and the hydride sites takes place in this complex.
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Treatment of trans-[Ir(H)(N)2(iPr)4(POCOP)(DMAP)][BAr4f] (2) with H2 (1 bar) under ambient conditions (298 K) results in the formation of a trans-[Ir(H)(η2-H2)(iPr)4(POCOP)(DMAP)][BAr4f] (3) complex. H-atom site exchange between the H2 and the hydride sites takes place in this complex.
The content of this RSS Feed (c) The Royal Society of Chemistry