N-Heterocyclic carbene-based porous polymer macroligand for the Ni-catalyzed C–H arylation of benzothiophenes

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY01263H, Communication
Open Access Open Access
Partha Samanta, Remi Beucher, Riddhi Kumari Riddhi, Alisa Ranscht, Florian M. Wisser, Elsje Alessandra Quadrelli, Jerome Canivet
A novel single-site Ni(NHC) catalyst embedded within a porous polymer has been developed for the heterogeneous direct C–H arylation of (benzo)thiophenes with unprecedented stability and recyclability.
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