Efficient additive-free formic acid dehydrogenation with a NNN–ruthenium complex

Catal. Sci. Technol., 2023, 13,5625-5631
DOI: 10.1039/D3CY00512G, Paper
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Pascal Knörr, Nicolas Lentz, Martin Albrecht
A new phosphine-free N,N,N-coordinated ruthenium complex featuring a pyridylidene amine (PYE) ligand catalyzes the dehydrogenation of formic acid with high activity; mechanistic studies reveal a critical role of the central N-donor of the NNN ligand.
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