Access to CF3-benzofulvenes via palladium-catalyzed cascade arylation/Trost–Oppolzer cyclization/double-bond isomerization

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D3CC06082A, Communication
Rami Sateesh, Jaggaraju Prudhviraj, Chiliveru Priyanka, Nagender Punna
Highly stereoselective synthesis of CF3-benzofulvenes has been achieved through a Pd-catalyzed cascade reaction involving three consecutive transformations such as arylation, Trost–Oppolzer type Alder-ene reaction, and double bond isomerization.
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