Synthesis, X-ray Characterization and DFT analysis of Dicyanidoaurate Telluronium salts: on the importance of charge assisted chalcogen bonds

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT02787B, Paper
Open Access Open Access
Simone Ghinato, Alessia Giordana, Eliano Diana, Rosa Maria Gomila, Emanuele Priola, Antonio Frontera
In this manuscript we report the synthesis and X-ray characterization of two cyanidoaurate telluronium salts, namely (3-fluorophenyl)(methyl)(phenyl)telluronium dicyanidoaurate [(3-F-Ph)(Me)(Ph)Te][Au(CN)2] (1) and methyldiphenyltelluronium dicyanidoaurate [(Me)(Ph)2Te][Au(CN)2] (2). In the solid state, the...
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