Melting pseudosymmetry and thermal expansion in 3-benzoylpropionic acid

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00940H, Paper
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tomasz Poręba, Marcin Świątkowski, Giorgia Confalonieri
3-Benzoylpropionic acid undergoes continuous transition associated with pseudosymmetry melting upon heating. The transition stems from a directional steric crowding, which refutes the recent premise of its colossal thermal expansion.
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