Pressure dependence of ionic conductivity in site disordered lithium superionic argyrodite Li6PS5Br

Energy Adv., 2023, Advance Article
DOI: 10.1039/D3YA00424D, Paper
Open Access Open Access
Vasiliki Faka, Matthias T. Agne, Paul Till, Tim Bernges, Marcel Sadowski, Ajay Gautam, Karsten Albe, Wolfgang G. Zeier
The activation volume of a mobile ion can be determined from pressure dependent conductivity measurements. In Br/S2− site disordered lithium argyrodites Li6PS5Br, the activation volume is increasing with increasing site disorder.
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