Competing quantum effects in heavy-atom tunnelling through conical intersections

Chem. Sci., 2023, 14,10777-10785
DOI: 10.1039/D3SC03706A, Edge Article
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wei Fang, Eric R. Heller, Jeremy O. Richardson
The geometric-phase effect appears in reactions which tunnel around conical intersections. Our novel instanton theories indicate that this plays an important role in certain charge-transfer reactions, even at room temperature.
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