Making one VIV substitution for Mo on classical [MoV2O4]2+ group: the first heterobimetallic Mo–V subunit in polyoxomolybdate–bisphosphonate family

Inorg. Chem. Front., 2023, 10,5782-5788
DOI: 10.1039/D3QI01268A, Research Article
Xiangyu Ren, Baokuan Chen, Gang Zhang, Yanfeng Bi, Lingling Dai, Guoping Yang
The first molybdovanadate cluster modified by bisphosphonate ligand with a new [MoVVIVO4] building unit is successfully synthesized. The VO bonds in this compound are demonstrated to play a pivotal role in the deep oxidation of dibenzothiophene.
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