Modification of Cu–ZnO–ZrO2 catalysts with La2O3 to quantitatively tune Cu+–Cu0 dual sites for hydrogenation of dimethyl adipate to produce 1,6-hexanediol

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY00747B, Paper
Xianlong Gao, Guoqing Zhao, Lei Miao, Lei Li, Zhirong Zhu
The strong electron donor–acceptor interaction between lanthanum and copper species retards the aggregation of the copper species, and inhibits the transformation of Cu2O to metallic Cu, thus maintaining a constant ratio of Cu+/(Cu0 + Cu+).
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