Group 14 metallole dianions as η5-coordinating ligands

Inorg. Chem. Front., 2023, 10,5509-5516
DOI: 10.1039/D3QI01342A, Chemistry Frontiers
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Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiaofei Sun, Peter W. Roesky
The coordination chemistry of group 14 metallole dianions, compared to monoanionic cyclopentadienides, is underexplored. This perspective reviews η5-coordination in group 14 metallole dianions, revealing their potential in organometallic chemistry.
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