Molecular modulation of nickel–salophen organic frameworks enables the selective photoreduction of CO2 at varying concentrations

Energy Environ. Sci., 2024, 17,2260-2268
DOI: 10.1039/D3EE04121B, Paper
Xiaohan Yu, Mingzi Sun, Tianran Yan, Lin Jia, Mingyu Chu, Liang Zhang, Wei Huang, Bolong Huang, Yanguang Li
Metal–salophen organic frameworks with dispersed metal centers and precise coordination environments were synthesized. The optimal sample exhibited great photocatalytic activity and near-unity CO selectivity over a wide range of CO2 concentrations.
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