One-dimensional infinite chain Ag(I) complex with high quantum yield and TADF property: prepared by metal ion adjustment

CrystEngComm, 2023, 25,5405-5412
DOI: 10.1039/D3CE00764B, Paper
Zhen-Zhou Sun, Fu-Zhen Hu, Cheng-Jie Gao, Wen-Long Mou, Guo Wang, Ning Zhu, Xun Pan, Zhong-Feng Li, Hong-Liang Han, Hongbing Fu, Xiu-Lan Xin, Lixiong Dai, Qiong-Hua Jin, Qi-Ming Qiu
The complex AgDpq exhibits excellent photophysical properties and TADF characteristics than Cu(I) complex, which is related to the unique one-dimensional infinite chain structure and the smaller contribution of metal to the excited states.
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