Programmable synthesis of difluorinated hydrocarbons from alkenes through a photocatalytic linchpin strategy

Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC03951J, Edge Article
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhi-Qi Zhang, Cheng-Qiang Wang, Long-Ji Li, Jared L. Piper, Zhi-Hui Peng, Jun-An Ma, Fa-Guang Zhang, Jie Wu
We have devised a general and versatile approach for the synthesis of diverse difluorinated alkanes and alkenes by utilizing readily accessible ClCF2SO2Na as a practical difluoromethylene linchpin.
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