MgO supported Cu catalyst can consistently drive the reverse water gas shift reaction with high activity. The high performance is attributed to the uniquely configured adsorbed CO₂ on the Cu/MgO catalyst. The adsorption behaviors of CO₂ were identified by in-situ infrared spectroscopy with coupled temperature programmed desorption and explained by theoretical calculation.

Abstract

Activation of inert CO₂ molecules for the reverse water gas shift (RWGS) reaction is tackled by incorporating magnesium oxide as a support material for copper, forming a Cu/MgO supported catalyst. The RWGS performance is greatly improved when compared with pure Cu or carbon supported Cu (Cu/C). Operating under a weight hourly space velocity (WHSV) of 300,000 mL ⋅ g⁻¹ ⋅ h⁻¹, the Cu/MgO catalyst demonstrates high activity, maintaining over 70 % equilibrium conversion and nearly 100 % CO selectivity in a temperature range of 300–600 °C. In contrast, both Cu/C and commercial Cu, even at ten-times lower WHSV, can only achieve up to 40 % of the equilibrium conversion and quickly deactivated due to sintering. Based on the studies of in-situ temperature resolved infrared spectroscopy and temperature programmed desorption, the improved RWGS performance is attributed to the unique adsorption behavior of CO₂ on Cu/MgO. Density functional theory studies provides a plausible explanation from a surface reaction perspective and reveals the spill-over property of CO₂ from MgO to Cu being critical.

The work presented in the manuscript describes a simple strategy for transforming thermally activated delayed fluorescent organic light-emitting diodes (TADF OLEDs) compound 10-(dibenzo[a,c]phenazin-11-yl)-10H-phenoxazine (DPZ-PXZ) into type I photosensitizer 10-(dibenzo[a,c]phenazin-11-yl)-10H-phenothiazine   (DPZ-PHZ) by strategically introducing sulfur atom in the photosensitizing core.  The synthesized compound DPZ-PHZ exhibits aggregation-induced enhancement (AIE) and through-space charge transfer (TSCT) characteristics and generates red emissive assemblies in mixed aqueous media.  The original compound DPZ-PXZ exhibits well-separated HOMO and LUMO levels and is reported to have highly efficient reverse intersystem crossing (RISC). In comparison, the incorporation of sulfur atom in the phenothiazine donor regulates the electronic communication between donor and acceptor units and promotes the intersystem crossing (ISC) in DPZ-PHZ molecules. Interestingly, compound DPZ-PHZ exhibits rapid activation of aerial oxygen for instant generation of superoxide radical anion. Backed by excellent type I photosensitizing activity, DPZ-PHZ assemblies have high catalytic potential for the synthesis of benzimidazoles, benzothiazoles and quinazolines derivatives under mild reaction conditions. The work presented in the manuscript provides an insight into the combination of heavy atom approach and TSCT for achieving adequate electronic communication between donor and acceptor units, balanced RISC/ISC, and stabilized-charge separated state for the development of efficient type I photosensitizing assemblies.

Nanosized cellulose, obtainable from food by-products, has great potential for use in the food industry. This review covers the specific extraction processes for nanocellulose and its various applications, including as a food additive, encapsulation agent, in green packaging, and as a functional coating.

Abstract

Rising global food prices and the increasing prevalence of food insecurity highlight the imprudence of food waste and the inefficiencies of the current food system. Upcycling food by-products holds significant potential for mitigating food loss and waste within the food supply chain. Food by-products can be utilized to extract nanocellulose, a material that has obtained substantial attention recently due to its renewability, biocompatibility, bioavailability, and a multitude of remarkable properties. Cellulose nanomaterials have been the subject of extensive research and have shown promise across a wide array of applications, including the food industry. Notably, nanocellulose possesses unique attributes such as a surface area, aspect ratio, rheological behavior, water absorption capabilities, crystallinity, surface modification, as well as low possibilities of cytotoxicity and genotoxicity. These qualities make nanocellulose suitable for diverse applications spanning the realms of food production, biomedicine, packaging, and beyond. This review aims to provide an overview of the outcomes and potential applications of cellulose nanomaterials derived from food by-products. Nanocellulose can be produced through both top-down and bottom-up approaches, yielding various types of nanocellulose. Each of these variants possesses distinctive characteristics that have the potential to significantly enhance multiple sectors within the commercial market.

A considerable amount of research has been carried out in recent years on synthesizing metal nanoclusters (NCs), which have wide applications in the field of optical materials with non-linear properties, bio-sensing, and catalysis. Aside from being structurally accurate, the atomically precise NCs possess well-defined compositions due to significant tailoring, both at the surface and the core, for certain functionalities. To illustrate the importance of atomically precise metal NCs for catalytic processes, this review emphasizes 1) the recent work on Cu, Ag, and Au NCs with their synthesis, 2) the parameters affecting the activity and selectivity of NCs catalysis, and 3) the discussion on the catalytic potential of these metal NCs. Additionally, metal NCs will facilitate the design of extremely active and selective catalysts for significant reactions by elucidating catalytic mechanisms at the atomic and molecular levels. Future advancements in the science of catalysis are expected to come from the potential to design NCs catalysts at the atomic level.

The FT-MF reactor with porous Ti/RuO₂-IrO₂@Pt as anode exhibits high degradation efficiency and low energy consumption in antibiotic degradation.

Abstract

In this study, a zero-gap flow-through microfluidic reactor was constructed for the degradation of tetracycline and norfloxacin in water using a porous Ti/RuO₂-IrO₂@Pt electrode as the anode and porous titanium plate as the cathode. The operation parameters included electrolyte type, electrolyte concentration, current density, initial concentration of pollutants and pH, were investigated. The degradation efficiency and energy consumption were calculated and compared with traditional electrolyzer. In the zero-gap flow-through microfluidic reactor, 100 % of both tetracycline and norfloxacin can be decomposed in 15 min, and high mineralization rate were achieved under the optimized reaction condition. And the reaction was consistent with pseudo-first-order kinetics with k value of 0.492 cm⁻¹ and 1.010 cm⁻¹, for tetracycline and norfloxacin, respectively. In addition, the energy consumption was 28.33 kWh ⋅ kg⁻¹ TC and 8.36 kWh ⋅ kg⁻¹ NOR, for tetracycline and norfloxacin, respectively, which was much lower than that of traditional electrolyzer. The LC–MS results showed that tetracycline underwent a series of demethylation, dehydration and deamination reactions, and the norfloxacin went through ring opening reaction, decarboxylation and hydroxylation reaction, and finally both produced CO₂ and H₂O.

Alcohol consumption in Aotearoa, New Zealand (NZ) was analysed through the use of Wastewater-based Epidemiology (WBE), covering ~40 % of the population over a six-month period in 2021. Factors including geographical (NZ locations, settlement size), temporal (day of the week, public holidays) and COVID-19 restrictions were found to significantly affect alcohol consumption in Aotearoa, NZ.

Abstract

Alcohol is an influential drug that has extensive societal impact. In Aotearoa New Zealand, there are a number of worrying trends related to alcohol consumption including rates of alcohol-related harm and violence and heavy episodic drinking. To understand and address these issues, alcohol consumption rates and related trends need to be understood. A wastewater-based epidemiology study was carried out over the course of six months (April–September 2021), sampling one week per month from ten catchment areas covering ~40 % of the national population. The average alcohol consumption was found to be 12.2 mL/person/day. Temporal and geographical trends in alcohol consumption were found; there was higher alcohol consumption on the weekends compared to weekdays, alcohol consumption was inversely related to settlement size, there was increased alcohol consumption due to public holidays and alcohol consumption was not seen to increase during COVID restrictions, however there was a notable change in the weekly trend during lockdowns. This application of alcohol WBE to Aotearoa New Zealand represents a comprehensive national study to understand alcohol consumption and its influences. The knowledge obtained will allow appropriate services and public policies to be reviewed to best serve communities.

SNW-1, a Schiff–base porous polymer, has been impregnated with ruthenium trichloride for acceptor–free dehydrogenation coupling (ADC) of secondary alcohols with γ-amino- and 2-aminobenzyl alcohols to give pyridines and quinolines. This heterogenous catalyst exhibited high catalytic efficiency over repeated cycles with wide functional group tolerance.

Abstract

A Schiff–base porous polymer has been impregnated with ruthenium trichloride for acceptor–free dehydrogenation coupling (ADC) of secondary alcohols with γ-amino- and 2-aminobenzyl alcohols to give pyridines and quinolines. This heterogenous catalyst exhibited high catalytic efficiency over repeated cycles with wide functional group tolerance.

A stable dialkylgermanone was generated by mixing a solid of the corresponding dialkylgermylene and gaseous N2O. While the dialkylgermanone is marginally persistent in solution and gradually converts to its head-to-tail dimer at room temperature, the addition of THF to the dialkylgermanone provided an isolable THF-coordinated dialkylgermanone. The THF-coordinated dialkylgermanone reacts with H2O, THF, and B(C6F5)3 similar to the corresponding base-free two-coordinate dialkylsilanone. The dialkylgermanone undergoes deoxygenation in the presence of triphenylphosphine to provide the corresponding germylene and olefination upon treatment with phosphaylide Ph3PCHPh to afford the corresponding Ge=C bond compound (germa-Wittig reaction).

In the realm of material science, carbon materials, especially olive-derived carbon (ODC), have become vital due to their sustainability and diverse properties. This review examines the sustainable extraction and use of ODC, a carbohydrate-rich by-product of olive biomass. We focus on innovative preparation techniques like pyrolysis, crucial for enhancing ODC's microstructure and surface properties. Variables such as activating agents, impregnation ratios, and pyrolysis conditions significantly influence these properties. ODC's high specific surface area renders it invaluable for applications in energy storage (in batteries and supercapacitors) and environmental sectors (water purification, hydrogen storage). Its versatility and accessibility underscore its potential for broad industrial use, marking it as a key element in sustainable development. This review provides a detailed analysis of ODC preparation methodologies, its various applications, and its role in advancing sustainable energy solutions. We highlight the novelty of ODC research and its impact on future studies, establishing this review as a crucial resource for researchers and practitioners in sustainable carbon materials. As global focus shifts towards eco-friendly solutions, ODC emerges as a critical component in shaping a sustainable, innovation-driven future.

Regioregular and random conjugated polymers based on a boron-fused azomethine unit were synthesized. Optical measurements and microscopic observation indicated the existence of aggregation domains in the spin-coated film of the regioregular polymer and no aggregation in that of the regiorandom polymer. Furthermore, fluorescence enhancement was brought about via aggregation disassembly of the regioregular polymer chains by thermal annealing treatment.

Abstract

Regioregular and random conjugated polymers based on a boron-fused azomethine unit were synthesized by Sonogashira–Hagihara cross coupling reaction. Although these polymers exhibited similar optical properties in the solution states, a distinct difference was observed in the aggregation forming ability in the film states; scanning electron microscope (SEM) observation indicated the existence of fiber-like aggregates in the spin-coated film of the regioregular polymer, while regiorandom polymer showed no aggregate in the film state. Accordingly, the UV–vis absorption spectrum of the regioregular polymer showed an increased shoulder peak due to the aggregate formation, whereas the random one showed no change. Furthermore, an absolute fluorescence quantum efficiency of the regioregular polymer was enhanced in response to the aggregate disassembly via thermal annealing treatment. In this study, we demonstrate that controlling regioregularity of the conjugated polymers can induce the different morphological structures and thermal-responsive behaviors. These findings could be beneficial for the design strategy and potential applications of thin-film optoelectronic devices with stimuli-responsive properties.